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Hosted by Al Roker, this 76th formal tree lighting ceremony will feature Beyonce, Tony Bennett, the Jonas Brothers, Harry Connick Jr., David Cook and Rosie O'Donnell, the network said Wednesday.
Other scheduled performers include Faith Hill, Rascal Flatts, "America's Got Talent" winner Neal E. Boyd and singer-songwriter Solange Knowles, as well as the Broadway Kids, students in a performing arts program founded by O'Donnell.
They will perform from Rockefeller Center's Art Deco plaza in the heart of Manhattan.
The live, hour-long special airs 8 p.m. EST Dec. 3.